Catalytic Activity of an Iron-Based Water Oxidation Catalyst: Substrate Effects of Graphitic Electrodes
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چکیده
منابع مشابه
Catalytic Activity of an Iron-Based Water Oxidation Catalyst: Substrate Effects of Graphitic Electrodes
The synthesis, characterization, and electrochemical studies of the dinuclear complex [(MeOH)Fe(Hbbpya)-μ-O-(Hbbpya)Fe(MeOH)](OTf)4 (1) (with Hbbpya = N,N-bis(2,2'-bipyrid-6-yl)amine) are described. With the help of online electrochemical mass spectrometry, the complex is demonstrated to be active as a water oxidation catalyst. Comparing the results obtained for different electrode materials sh...
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Water Oxidation at Hematite Photoelectrodes with an Iridium-Based Catalyst
The iridium complex [Cp*Ir(H2O)3](SO4) was used as an organometallic source for the electrodeposition of iridium oxide onto Fe2O3. The new iridium-containing electrode allowed us to study the coupling between the photocatalytic properties of hematite and the electrocatalytic properties of the iridium-based material. A cathodic shift of the photocurrent for water oxidation upon electrodeposition...
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ژورنال
عنوان ژورنال: ACS Catalysis
سال: 2018
ISSN: 2155-5435,2155-5435
DOI: 10.1021/acscatal.7b03284